X-Ray Crystal Structure of a Heterobimetallic Al-Zn-Oxide Complex

In: Chemical Communications, Jg. 47 (2011) ; Nr. 9, S. 2676-2678
ISSN: 0022-4936
Zeitschriftenaufsatz / Fach: Chemie
Fakultät für Chemie » Anorganische Chemie
Abstract:
OH/R (R = H, Me, i-Bu) exchange was observed in reactions of [MesnacnacZn(μ-OH)]2 (1) with metal complexes LnMR, whereas DippnacnacAl(Me)OH reacts with MesnacnacZnH with elimination of H2 and formation of the heterobimetallic Al–Zn-oxide complex MesnacnacZnOAl(Me)Dippnacnac 2.