Syntheses and Structures of Triazides of Heavy Group 15 Elements

In: Chemical Communications, Jg. 47 (2011) ; Nr. 12, S. 3401-3403
ISSN: 1364-548X
Zeitschriftenaufsatz / Fach: Chemie
Fakultät für Chemie » Anorganische Chemie
Synthesis of group 15-triazides E(N3)3 (E = Sb 1, Bi 2) and Py2–Bi(N3)33 (Py = pyridine). Single crystals of 1 were in situ grown by an IR-laser-assisted technique on the diffractometer. The structure of 3, which represents the first structurally characterized neutral Bi-triazide, is influenced by crystal packing effects according to DFT calculations.