Direct Carboxylation of Zincocene Cp*2Zn,

In: European Journal of Inorganic Chemistry, Jg. 2011 (2011) ; Nr. 27, S. 4157-4160
ISSN: 1099-0682
Zeitschriftenaufsatz / Fach: Chemie
Fakultät für Chemie » Anorganische Chemie
The reaction of zincocene Cp*2Zn with CO2 proceeds with the formation of [Zn4(μ4-O)(O2CCp*)6] (1), which was characterized by NMR (1H, 13C) and IR spectroscopy as well as by elemental analysis and single-crystal X-ray diffraction. The solid-state structure of 1 is comparable to that previously observed for basic zinc acetate. In contrast to many previously reported CO2 activation reactions, the formation of 1 occurred without the use of any additional transmetalation catalyst.