Syntheses and Structural Characterization of Antimony Polyazides

In: Chemistry - A European Journal, Jg. 17 (2011) ; Nr. 41, S. 11394-11398
ISSN: 1521-3765
Zeitschriftenaufsatz / Fach: Chemie
Fakultät für Chemie » Anorganische Chemie
The synthesis of antimony polyazides and structural characterization of the pentaazidoantimonite [Sb(N3)5]2− dianion, which is without precedent in Group 15 polyazide chemistry, is reported (see scheme).