First Structural Characterization of Neutral, Base-Stabilized Group 15-Pentaazides - Single Crystal X-ray Structures of dmap-As(N3)5

In: Inorganic Chemistry, Jg. 51 (2012) ; Nr. 10, S. 5897-5902
ISSN: 0020-1669, 1520-510X
Zeitschriftenaufsatz / Fach: Chemie
Fakultät für Chemie » Anorganische Chemie
Abstract:
Two neutral group 15-pentaazides dmap-As(N3)5 (1) and dmap-Sb(N3)5 (2) were synthesized and structurally characterized for the first time (dmap = 4-dimethylaminopyridine). Base-stabilization was confirmed to be very suitable for the kinetic stabilization of highly explosive covalent main group polyazides.