Solid State and Solution Studies on α, β-Diketiminate Zinc Hydride Complex
In: Zeitschrift für Naturforschung, Jg. 64b (2009), S. 1397
Zeitschriftenaufsatz / Fach: Chemie
[MesnacnacZn(μ-H)]2 (1) was synthesized by reaction of MesnacnacZnI with either an equimolar amount of KNH(iPr)BH3 or an excess of NaH and characterized by multinuclear NMR and IR spectroscopy as well as X-ray diffraction. Two polymorphs of 1 were found and their structures determined on single crystals.