Schulz, Stephan; Eisenmann, Tamara; Schuchmann, Daniella; Bolte, Michael; Kirchner, Michael; Boese, Roland; Spielmann, Jan; Harder, Sjoerd:

Solid State and Solution Studies on α, β-Diketiminate Zinc Hydride Complex

In: Zeitschrift für Naturforschung, Jg. 64b (2009), S. 1397
ISSN: 0044-3166
Zeitschriftenaufsatz / Fach: Chemie
[MesnacnacZn(μ-H)]2 (1) was synthesized by reaction of MesnacnacZnI with either an equimolar
amount of KNH(iPr)BH3 or an excess of NaH and characterized by multinuclear NMR and IR
spectroscopy as well as X-ray diffraction. Two polymorphs of 1 were found and their structures determined
on single crystals.