Schulz, Stephan; Schmidt, Sarah; Bläser, Dieter; Boese, Roland; Bolte, Michael:
Synthesis and Structural Characterization of New Zinc Amidinate Complexes
2010
In: Organometallics, Band 29 (2010), S. 6097
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Synthesis and Structural Characterization of New Zinc Amidinate Complexes
Autor(in):
Schulz, Stephan im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen; Schmidt, Sarah im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen; Bläser, Dieter; Boese, Roland; Bolte, Michael
Erscheinungsjahr:
2010
Erschienen in:
Organometallics, Band 29 (2010), S. 6097
ISSN:
DOI:

Abstract:

The synthesis and reactivity of heteroleptic zinc complexes of the type LZnX (X = Me, I) containing amidinate ligands L of varying steric bulk were investigated. Complexes of the type LZnMe, which were obtained from the homoleptic complexes L2Zn upon reaction with ZnMe2, react with iodine with subsequent formation of LZnI. Single-crystal X-ray structures of the amidinate zinc complexes [{MeC(Ni-Pr)2}ZnMe]2, 1, [{MeC(Ni-Pr)2}ZnI]2LiI(OEt)2, 3, [t-BuC(NDipp)2]ZnMe, 5, [t-BuC(NDipp)2]ZnMe(t-BuPy), 6, [{t-BuC(NDipp)2}Zn(μ-I)]2, 7, and [t-BuC{N(H)Dipp}2][Al{OC(CF3)3}4], 8, are reported.