Schulz, Stephan; Schmidt, Sarah; Bläser, Dieter; Boese, Roland; Bolte, Michael:
Synthesis and Structural Characterization of New Zinc Amidinate Complexes
2010
In: Organometallics, Band 29 (2010), S. 6097
Artikel/Aufsatz in Zeitschrift2010Chemie
Titel:
Synthesis and Structural Characterization of New Zinc Amidinate Complexes
Autor(in):
Schulz, StephanLSF; Schmidt, SarahLSF; Bläser, Dieter; Boese, Roland; Bolte, Michael
Erscheinungsjahr
2010
DOI:

Abstract:

The synthesis and reactivity of heteroleptic zinc complexes of the type LZnX (X = Me, I) containing amidinate ligands L of varying steric bulk were investigated. Complexes of the type LZnMe, which were obtained from the homoleptic complexes L2Zn upon reaction with ZnMe2, react with iodine with subsequent formation of LZnI. Single-crystal X-ray structures of the amidinate zinc complexes [{MeC(Ni-Pr)2}ZnMe]2, 1, [{MeC(Ni-Pr)2}ZnI]2LiI(OEt)2, 3, [t-BuC(NDipp)2]ZnMe, 5, [t-BuC(NDipp)2]ZnMe(t-BuPy), 6, [{t-BuC(NDipp)2}Zn(μ-I)]2, 7, and [t-BuC{N(H)Dipp}2][Al{OC(CF3)3}4], 8, are reported.