Schulz, Stephan; Eisenmann, Tamara; Schmidt, Sarah; Bläser, Dieter; Westphal, Ulrich; Boese, Roland:

Reactions of a β-Diketiminate Zinc Hydride Complex with Heterocumulenes

In: Chemical Communication, Jg. 46 (2010), S. 7226
Zeitschriftenaufsatz / Fach: Chemie
The β-diketiminate zinc hydride MesnacnacZnH (1) reacts with CO2, C(Ni-Pr)2 and t-BuNCO at ambient temperature with insertion into the Zn–H bond and subsequent formation of the corresponding formato (2), formamido (3) and formamidinato (4) complexes.