Schulz, Stephan; Flörke, Ulrich:
Base-stabilized dimeric organozinc alkoxides
2010
In: Journal of Chemical Crystallography, Band 40 (2010), S. 888
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Base-stabilized dimeric organozinc alkoxides
Autor(in):
Schulz, Stephan im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen; Flörke, Ulrich
Erscheinungsjahr
2010
Erschienen in:
Journal of Chemical Crystallography, Band 40 (2010), S. 888
DOI

Abstract:

Dimeric, base-stabilized organozinc alkoxides [dmap-Zn(R)μ-OR]2 (R = Et 1; i-Pr 2), were obtained from reactions of ZnR2 and 4-dimethylaminopyridine (dmap) in the presence of O2. Their solid state structures were determined by single crystal X-ray diffraction studies. 1 is triclinic, space group P-1 with a = 8.0639(10) Å, b = 8.3082(11) Å, c = 10.4545(13) Å, α = 70.846(2)°, β = 72.316(2)°, γ = 81.505(2)° and Z = 1. 2 is triclinic, space group P-1 with a = 8.6381(6) Å, b = 9.2773(7) Å, c = 10.2186(7) Å, α = 112.094(1)°, β = 103.040(1)°, γ = 92.598(1)° and Z = 1.