Schulz, Stephan; Kuczkowski, Andreas; Nieger, Martin:

Lewis acid-base adduct Me3Sb-Ga(t-Bu)3

In: Journal of Chemical Crystallography, Jg. 40 (2010), S. 1163
Zeitschriftenaufsatz / Fach: Chemie
The simple Lewis acid–base adduct Me3Sb–Ga(t-Bu)3 1 was prepared by reaction of t-Bu3Ga and SbMe3 in 1:1 M ratio. 1 was fully characterized by multinuclear NMR spectroscopy (1H, 13C). In addition, its solid state structure was determined by single crystal X-ray diffraction studies. 1 is monoclinic, space group P21 /n with a = 8.4895(2) Å, b = 12.9303(4) Å, c = 17.9976(5) Å, β = 97.472(2)° and Z = 4.