Zinc Carbodiimide Cluster Complexes - Synthesis, X-Ray Crystal Structure and Reaction Mechanism

In: Organometallics, Jg. 28 (2009), S. 4371
Zeitschriftenaufsatz / Fach: Chemie
Abstract:
Reactions of Me2Zn with carbodiimides C(NR)2 in different molar ratios at elevated temperature were investigated, a possible reaction mechanism was identified, and the single-crystal X-ray structures of polynuclear amidinate zinc complexes {C[C(NCy)2ZnMe]4}, 1, {C[C(NCy)2ZnMe]3(ZnMe)}, 3, and {C[C(NCy)2ZnMe]3(ZnMe)(MeZnOMe)}, 5, are reported.

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