Schulz, Stephan; Eisenmann, Tamara; Westphal, Ulrich; Schmidt, Sarah; Flörke, Ulrich:

Synthesis and Characterization of ß-Diketiminate Zinc Complexes

In: Zeitschrift für Anorganische und Allgemeine Chemie, Jg. 635 (2009), S. im Druck
Zeitschriftenaufsatz / Fach: Chemie
Abstract:
The monomeric beta-diketiminate zinc complex (Mes)NacNacZnMe 1 (MesNacNac = {[2,6-(2,4,6-Me3-C6H2)N(Me)C)]2CH}) was obtained in almost quantitative yield from the reaction of ZnMe2 with (Mes)NacNacH. Reaction of 1 with either Me3NHCl or a solution of HCl in Et2O yielded (Mes)NacNacZnCl 2, whereas (Mes)NacNacZnI 3 was obtained from the reaction of 1 with I2. 1 - 3 were characterized by elemental analyses, mass and multinuclear (1H, 13C{1H}) NMR spectroscopy (1H, 13C), 3·THF also by single crystal X-ray analysis.