Nelles, J.; Sendor, D.; Ebbers, A.; Petrat, F.M.; Wiggers, Hartmut; Schulz, Christof; Simon, U.:
Functionalization of silicon nanoparticles via hydrosilylation with 1-alkenes
2007
In: Colloid Polym. Sci., Jg. 285 (2007), Heft 7, S. 729 - 736
Artikel/Aufsatz in Zeitschrift2007Maschinenbau
Titel:
Functionalization of silicon nanoparticles via hydrosilylation with 1-alkenes
Autor(in):
Nelles, J.; Sendor, D.; Ebbers, A.; Petrat, F.M.; Wiggers, HartmutLSF; Schulz, ChristofLSF; Simon, U.
Erscheinungsjahr
2007

Abstract:

Studies focusing on the functionalization of the surface of free silicon nanoparticles are presented. This functionalization is applied to hydrogen-terminated silicon nanoparticles to evaluate how far the well-known soln.-phase chem. of thermal-, radical-, Lewis acid- and UV light-mediated hydrosilylation can be applied to the surface chem. of silicon nanoparticles. The efficiencies of hydrosilylation for thermal-, radical- and Lewis acid-mediated reactions on silicon nanoparticles surfaces, deduced from the intensity of the n(Si-H) absorption, are found to be comparable.