Baldridge, Kim K.; Biggs, Bluegrass; Blaser, Dieter; Boese, Roland; Gilbertson, Robert D.; Haley, Michael M.; Maulitz, Andreas H.; Siegel, Jay S.:
X-ray crystal and ab initio structure of 3-ethynylcyclopropene: a curiously short carbon-carbon double bond.
1998
In: Chemical Communications (Cambridge), Heft 10, S. 1137 - 1138
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
X-ray crystal and ab initio structure of 3-ethynylcyclopropene: a curiously short carbon-carbon double bond.
Autor(in):
Baldridge, Kim K.; Biggs, Bluegrass; Blaser, Dieter; Boese, Roland im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen; Gilbertson, Robert D.; Haley, Michael M.; Maulitz, Andreas H.; Siegel, Jay S.
Erscheinungsjahr:
1998
Erschienen in:
Chemical Communications (Cambridge), Heft 10, S. 1137 - 1138
ISSN:

Abstract:

The X-ray crystal structure of 3-ethynylcyclopropene shows that the carbon-carbon double bond of the mol. is unusually short [1.255(2) .ANG.], whereas theor. calcns. suggest a relative insensitivity of the bond length to adjacent orbital interactions.