Billups, W.e.; Haley, Michael M.; Boese, Roland; Blaser, Dieter:
Synthesis of the bicyclopropenyls.
1994
In: Tetrahedron (Tetrahedron), Jg. 50 (1994), Heft 36, S. 10693 - 10700
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Synthesis of the bicyclopropenyls.
Autor(in):
Billups, W.e.; Haley, Michael M.; Boese, Roland im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen; Blaser, Dieter
Erscheinungsjahr:
1994
Erschienen in:
Tetrahedron (Tetrahedron), Jg. 50 (1994), Heft 36, S. 10693 - 10700
ISSN:

Abstract:

Bicyclopropenyls (I,II,III) have been synthesized by the vacuum gas-phase elimination of b-halocyclopropylsilane precursors over solid fluoride. Bicycloprop-2-enyl I and bicycloprop-1,2'-enyl II were isolated and characterized using std. spectroscopic techniques whereas bicycloprop-1-enyl III could only be generated in situ and trapped by cyclopentadiene.