Non-planar structures of Et3N and Pri3N: a contradiction between the X-ray, and NMR and electron diffraction data for Pri3N.
The crystal structures of Et3N and Pri3N were detd. by x-ray anal. using the in situ crystn. technique for single crystal growth on the diffractometer; both have a pyramidal configuration of the N atom, even Pri3N, which was considered to be planar in accord with electron diffraction and NMR data. Crystallog. data are given.
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