Boese, Roland; Blaeser, Dieter; Niederpruem, Norbert; Nuesse, Markus; Brett, Waldemar A.; Schleyer, Paul v. R.; Buehl, Michael; Van Eikema Hommes, Nicolaas J.R.:

Strong hyperconjugative and inductive effects in C-C-X (X = Main group element) bond angles: crystal structure and ab initio calculation of triethylborane.

In: Angewandte Chemie, Jg. 104 (1992) ; Nr. 3, S. 356-8
ISSN: 0044-8249
Zeitschriftenaufsatz / Fach: Chemie
Abstract:
The crystal structures and ab initio MO calcns. of Et3B and NaBEt4 were discussed. The large C-C-B bond angles of Et3B and NaBEt4 were explained by strong hyperconjugation and inductive effects.