Strong hyperconjugative and inductive effects in C-C-X (X = Main group element) bond angles: crystal structure and ab initio calculation of triethylborane.
In: Angewandte Chemie, Jg. 104 (1992) ; Nr. 3, S. 356-8
Zeitschriftenaufsatz / Fach: Chemie
The crystal structures and ab initio MO calcns. of Et3B and NaBEt4 were discussed. The large C-C-B bond angles of Et3B and NaBEt4 were explained by strong hyperconjugation and inductive effects.