Boese, Roland; Blaeser, Dieter; Petz, Wolfgang:
[Fe(CO)4C(O)NMe2][C(NMe2)3]. The first structure determination on an organometallic compound with the carbenium ion [C(NMe2)3]+.
1988
In: Zeitschrift fuer Naturforschung, B: Chemical Sciences, Jg. 43 (1988), Heft 8, S. 945 - 948
Artikel/Aufsatz in Zeitschrift1988Chemie
Titel:
[Fe(CO)4C(O)NMe2][C(NMe2)3]. The first structure determination on an organometallic compound with the carbenium ion [C(NMe2)3]+.
Autor(in):
Boese, RolandLSF; Blaeser, Dieter; Petz, Wolfgang
Erscheinungsjahr
1988

Abstract:

The crystal structure of the carbamoyl complex [(CO)4FeC(O)NMe2][C(NMe2)3] is described. The cation has a planar CN3 array with sp2 hybridized C and N atoms. The carbamoyl group of the anion occupies an axial position in the trigonal bipyramidal environment of the iron atom.