Boese, Roland; Blaeser, Dieter; Petz, Wolfgang:

[Fe(CO)4C(O)NMe2][C(NMe2)3]. The first structure determination on an organometallic compound with the carbenium ion [C(NMe2)3]+.

In: Zeitschrift fuer Naturforschung, B: Chemical Sciences, Jg. 43 (1988) ; Nr. 8, S. 945-948
ISSN: 0932-0776
Zeitschriftenaufsatz / Fach: Chemie
The crystal structure of the carbamoyl complex [(CO)4FeC(O)NMe2][C(NMe2)3] is described. The cation has a planar CN3 array with sp2 hybridized C and N atoms. The carbamoyl group of the anion occupies an axial position in the trigonal bipyramidal environment of the iron atom.