Boese, Roland; Haegele, Gerhard; Kueckelhaus, Wolfgang:
Menthyl-substituted phosphorus compounds. VIII. Di-D,L-menthylphosphinothioyl chloride: crystal and molecular structure compared to the structure in solution.
1988
In: Chemiker-Zeitung, Jg. 112 (1988), Heft 10, S. 301 - 304
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Menthyl-substituted phosphorus compounds. VIII. Di-D,L-menthylphosphinothioyl chloride: crystal and molecular structure compared to the structure in solution.
Autor(in):
Boese, Roland im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen; Haegele, Gerhard; Kueckelhaus, Wolfgang
Erscheinungsjahr:
1988
Erschienen in:
Chemiker-Zeitung, Jg. 112 (1988), Heft 10, S. 301 - 304
ISSN:

Abstract:

The P-pseudoepimers of D-menthyl-L-menthylthiophosphorylchloride were prepd. and investigated by x-ray- and NMR-studies. The enantiotopic menthyl groups are arranged with the pseudochiral P-atom nearly in an all-trans-chain. Stereospecific NMR-parameters are evident for the similarity of crystal structure and mol. geometry in soln.