Menthyl-substituted phosphorus compounds. VIII. Di-D,L-menthylphosphinothioyl chloride: crystal and molecular structure compared to the structure in solution.
In: Chemiker-Zeitung, Jg. 112 (1988) ; Nr. 10, S. 301-304
Zeitschriftenaufsatz / Fach: Chemie
The P-pseudoepimers of D-menthyl-L-menthylthiophosphorylchloride were prepd. and investigated by x-ray- and NMR-studies. The enantiotopic menthyl groups are arranged with the pseudochiral P-atom nearly in an all-trans-chain. Stereospecific NMR-parameters are evident for the similarity of crystal structure and mol. geometry in soln.