Boese, Roland; Paetzold, Peter; Tapper, Alexander:
[Bis(trimethylsilyl)methylene](diisopropylamino)borane: an allene-type N:B:C system.
1987
In: Chemische Berichte (Chem.Ber.), Jg. 120 (1987), Heft 6, S. 1069 - 1071
Artikel/Aufsatz in Zeitschrift1987Chemie
Titel:
[Bis(trimethylsilyl)methylene](diisopropylamino)borane: an allene-type N:B:C system.
Autor(in):
Boese, RolandLSF; Paetzold, Peter; Tapper, Alexander
Erscheinungsjahr
1987

Abstract:

Thermolysis of (Me2CH)2NBFC(SiMe3)3 at 520 Deg gave 67% (Me2CH)2N:B:C(SiMe3)2 (I), via elimination of Me3SiF, as a colorless storable liq. Cycloaddns. of I with PhCHO and Me3SiN3 gave 51% oxaboretane II and 15% triazaborole III. The crystal structure of I is reported.