Boese, Roland; Paetzold, Peter; Tapper, Alexander:

[Bis(trimethylsilyl)methylene](diisopropylamino)borane: an allene-type N:B:C system.

In: Chemische Berichte (Chem.Ber.), Jg. 120 (1987) ; Nr. 6, S. 1069-1071
ISSN: 0009-2940
Zeitschriftenaufsatz / Fach: Chemie
Thermolysis of (Me2CH)2NBFC(SiMe3)3 at 520 Deg gave 67% (Me2CH)2N:B:C(SiMe3)2 (I), via elimination of Me3SiF, as a colorless storable liq. Cycloaddns. of I with PhCHO and Me3SiN3 gave 51% oxaboretane II and 15% triazaborole III. The crystal structure of I is reported.