Boese, Roland; Polk, Michael; Blaeser, Dieter:
Cooperative effect in the phase transformation of triethylcyclotriboroxane.
1987
In: Angewandte Chemie, Jg. 99 (1987), Heft 3, S. 239 - 241
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Cooperative effect in the phase transformation of triethylcyclotriboroxane.
Autor(in):
Boese, Roland im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen; Polk, Michael; Blaeser, Dieter
Erscheinungsjahr:
1987
Erschienen in:
Angewandte Chemie, Jg. 99 (1987), Heft 3, S. 239 - 241
ISSN:

Abstract:

The phase transition at -82 Deg in the title compd. was studied by x-ray diffractometry. The lattice parameters are given for the 2 phases at several temps. on either side of the transition. The transition is 1st-order. In both phases the mol. has a planar D3h symmetry. The transition involves ordering. The ordering mechanism is described in terms of cooperative interactions of the mol.