Breit, Bernhard; Memmesheimer, Holger; Boese, Roland; Regitz, Manfred:
Organophosphorus compounds. 53. Cyclopropylidene-methylene-diphosphines - new cross-conjugated phosphapolyenes.
1992
In: Chemische Berichte (Chem.Ber.), Jg. 125 (1992), Heft 3, S. 729 - 732
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Organophosphorus compounds. 53. Cyclopropylidene-methylene-diphosphines - new cross-conjugated phosphapolyenes.
Autor(in):
Breit, Bernhard; Memmesheimer, Holger; Boese, Roland im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen; Regitz, Manfred
Erscheinungsjahr:
1992
Erschienen in:
Chemische Berichte (Chem.Ber.), Jg. 125 (1992), Heft 3, S. 729 - 732
ISSN:

Abstract:

The reaction of chloromethylenephosphines ClP:CRSiMe3 (R = SiMe3, Ph) with the inverse cyclopropylidenephosphines I (R1 = CMe3, adamantyl) leads to the formation of the title compds. II as a new class of cross-conjugated phosphapolyenes. The structure of II (R1 = CMe3, R = SiMe3) was confirmed by x-ray crystallog.