Brown, David S.; Delville-Desbois, Marie Helene; Boese, Roland; Vollhardt, K. Peter C.; Astruc, Didier:
Electron-reservoir complexes [FeICp(arene)] as selective initiators for a new electrocatalyzed reaction: synthesis of fulvalene bridged homo- and heterodinuclear zwitterions.
1994
In: Angewandte Chemie, Jg. 106 (1994), Heft 6, S. 715 - 717
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Electron-reservoir complexes [FeICp(arene)] as selective initiators for a new electrocatalyzed reaction: synthesis of fulvalene bridged homo- and heterodinuclear zwitterions.
Autor(in):
Brown, David S.; Delville-Desbois, Marie Helene; Boese, Roland im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen; Vollhardt, K. Peter C.; Astruc, Didier
Erscheinungsjahr:
1994
Erschienen in:
Angewandte Chemie, Jg. 106 (1994), Heft 6, S. 715 - 717
ISSN:

Abstract:

The electron transfer chain catalyzed redox reaction via the intramol. disproportionation of binuclear carbonylfulvene complexes in the presence of PR3 to give the title compds. is described. Thus, [FeICp(C6Me6)]-catalyzed intramol. disproportionation of carbonylfulvene complexes I (M1 = Mo, W, Fe, Ru; M2 = Mo, W; n = 2, 3) in THF/DME gave fulvalene-bridged heterodinuclear complexes II. The crystal structure of II (M1 = Fe, n = 2, R = Me) was detd.