Fillaut, Jean Luc; Boese, Roland; Astruc, Didier:
Tentacled sandwiches: iron-mediated hexa-p-alkoxybenzylation of hexamethylbenzene and x-ray crystal structure of [Fe(h5-C5H5)C6(CH2CH2-p-C6H4OEt)6]+PF6-.
1992
In: Synlett, Heft 1, S. 55 - 56
Artikel/Aufsatz in Zeitschrift1992Chemie
Titel:
Tentacled sandwiches: iron-mediated hexa-p-alkoxybenzylation of hexamethylbenzene and x-ray crystal structure of [Fe(h5-C5H5)C6(CH2CH2-p-C6H4OEt)6]+PF6-.
Autor(in):
Fillaut, Jean Luc; Boese, RolandLSF; Astruc, Didier
Erscheinungsjahr
1992
Erschienen in:
Titel:
Synlett
in:
Heft 1, S. 55 - 56
ISSN:

Abstract:

The prepn. of a series of tentacled organoiron and org. compds. resulting from the Fe(h5-C5H5)+ mediated hexa-p-alkoxybenzylation of hexamethylbenzene is achieved in one pot with variable chain lengths; the x-ray crystal structure of [Fe(h5-C5H5)C6(CH2CH2-p-EtOC6H4)6]+ PF6- (I; R = Et) shows two proximal chains and four distal ones.