Herberich, G.e.; Ganter, C.; Wesemann, L.; Boese, R.:

A novel slipped triple-decker complex with a 3,4-diborafulvene as bridging ligand.

In: Journal of Organometallic Chemistry, Jg. 394 (1990) ; Nr. 1-3, S. C1-5
ISSN: 0022-328X
Zeitschriftenaufsatz / Fach: Chemie
Abstract:
Reaction of the 3,4-diboratafulvene deriv. Li2[CH2C[CHB(NEt2)]2] (I) with [RhCl(COD)]2 (COD = cyclooctadiene) gives m-[1-5-h5:1,2,5,6-h4-[CH2C[CHB(NEt2)]2]][Rh(h-COD)]2 (II), the first 3,4-diborafulvene complex which possesses a doubly-opened triple-decker structure with a bridging 3,4-diborafulvene ligand. The crystal structure of II was detd. I serves as a gallium nitride precursor.

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