Herberich, G.e.; Ganter, C.; Wesemann, L.; Boese, R.:
A novel slipped triple-decker complex with a 3,4-diborafulvene as bridging ligand.
1990
In: Journal of Organometallic Chemistry, Jg. 394 (1990), Heft 1-3, S. C1 - 5
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
A novel slipped triple-decker complex with a 3,4-diborafulvene as bridging ligand.
Autor(in):
Herberich, G.e.; Ganter, C.; Wesemann, L.; Boese, R. im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen
Erscheinungsjahr:
1990
Erschienen in:
Journal of Organometallic Chemistry, Jg. 394 (1990), Heft 1-3, S. C1 - 5
ISSN:

Abstract:

Reaction of the 3,4-diboratafulvene deriv. Li2[CH2C[CHB(NEt2)]2] (I) with [RhCl(COD)]2 (COD = cyclooctadiene) gives m-[1-5-h5:1,2,5,6-h4-[CH2C[CHB(NEt2)]2]][Rh(h-COD)]2 (II), the first 3,4-diborafulvene complex which possesses a doubly-opened triple-decker structure with a bridging 3,4-diborafulvene ligand. The crystal structure of II was detd. I serves as a gallium nitride precursor.