Knoelker, Hans Joachim; Bauermeister, Michael; Pannek, Joern Bernd; Blaeser, Dieter; Boese, Roland:

Transition metal-diene complexes in organic synthesis. 13. Highly chemo- and stereoselective oxidations of tricarbonyliron-cyclohexadiene complexes: synthesis of 4-deoxycarbazomycin B.

In: Tetrahedron (Tetrahedron), Jg. 49 (1993) ; Nr. 4, S. 841-862
ISSN: 0040-4020
Zeitschriftenaufsatz / Fach: Chemie
Chemo- and stereoselectivity in oxidns. of tricarbonyl(5-aryl-h4-1,3-cyclohexadiene)iron complexes, e.g., I, is achieved by the choice of the oxidizing reagent. This procedure provides Fe-complexed 4a,9a-dihydro-9H-carbazoles, 4b,8a-dihydrocarbazol-3-ones, and 4-deoxycarbazomycin B.