Koelle, U.; Kossakowski, J.; Boese, R.:

(Pentamethylcyclopentadienyl)ruthenium alkoxo complexes. III. Comparison of the molecular structures of [Cp*RuOMe]2 und [(Cp*Ru)3(m3-OMe)2]PF6.

In: Journal of Organometallic Chemistry, Jg. 378 (1989) ; Nr. 3, S. 449-455
ISSN: 0022-328X
Zeitschriftenaufsatz / Fach: Chemie
The formation of a trinuclear dimethoxo cluster cation [(Cp*Ru)3(m3-OMe)2]+ through protic degrdn. of the neutral dimeric methoxo complex [Cp*RuOMe]2 is described. Both compds. were characterized by an x-ray diffraction study.