Koester, Roland; Seidel, Guenter; Boese, Roland; Wrackmeyer, Bernd:
Boron compounds. 80. 2,5-Dihydro-1,2,5-thiasilaboroles. Preparation and complexations.
1988
In: Chemische Berichte (Chem.Ber.), Jg. 121 (1988), Heft 4, S. 709 - 721
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Boron compounds. 80. 2,5-Dihydro-1,2,5-thiasilaboroles. Preparation and complexations.
Autor(in):
Koester, Roland; Seidel, Guenter; Boese, Roland im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen; Wrackmeyer, Bernd
Erscheinungsjahr:
1988
Erschienen in:
Chemische Berichte (Chem.Ber.), Jg. 121 (1988), Heft 4, S. 709 - 721
ISSN:

Abstract:

Title compds. I (R = Me, CMe:CH2) were prepd. by reaction of Me2SiClCR:CEtBEtCl with Li2S, Na2S, or (Me3Si)2S. Complexes of I with AlCl3, Lewis bases (e.g., g-picoline N-oxide), and transition metal compds. (e.g., Cr and Fe carbonyls) were prepd. and their structures examd. Sandwich complexes were obtained from I and (cyclododecatriene)nickel, and one was subjected to x-ray anal. Reactions of I with MeOH, AcOH, and acetylacetone were studied, the last resulting in S/O exchange.