Krebs, Adolf; Pforr, Karl-Ingo; Raffay, Walter; Thoelke, Bernd; Koenig, Wilfried A.; Hardt, Ingo; Boese, Roland:

A stable hetero-trans-cycloheptene.

In: Angewandte Chemie, International Edition in English, Jg. 36 (1997) ; 1/2, S. 159-160
ISSN: 0570-0833
Zeitschriftenaufsatz / Fach: Chemie
A multistep synthesis of stable trans-1,1,3,3,6,6-hexamethyl-1-sila-4-cycloheptene I starting from the dialkylation of Me2SiCl2 with 3-bromo-2,2-dimethyl-1-propanol is reported. I was characterized by x-ray crystallog., and its reactivity with Ph azide and furan was examd.