Imidazole derivatives. Part 43. Synthesis and properties of 2-cyanimino-1,3-dimethylimidazoline.
2-Cyanimino-1,3-dimethylimidazoline (I) is obtained from 1,3-dimethyl-2-iminoimidazoline and BrCN. With Mo(CO)6, I forms the carbonyl complex I.Mo(CO)5. The crystal structure of I [monoclinic, P21/m, a 6.696(1), b 6.573(1), c 8.564(1) .ANG., b 112.95(1) Deg, V 347.1(1) .ANG.3, Z 2] is reported. The properties of I are discussed on comparison with those of (H2N)2C:NCN.
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