Kuhn, Norbert; Horn, Eva Maria; Boese, Roland; Blaeser, Dieter:

Heterocycles as ligands. VI. The bridging coordination of 1,1'-diazaferrocene in a dinuclear silver complex - an uncommon structure.

In: Chemische Berichte (Chem.Ber.), Jg. 122 (1989) ; Nr. 12, S. 2275-2277
ISSN: 0009-2940
Zeitschriftenaufsatz / Fach: Chemie
Reaction of octamethyldiazaferrocene tetramethylpyrrole adduct with AgBF4 in MeOH gave 47% title complex I. The crystal structure detn. of I.2MeOH shows that the bridging coordination mode of diazaferrocene ligands have a nearly linear geometry at Ag atoms.