Kuhn, Norbert; Jendral, Kai; Boese, Roland; Blaeser, Dieter:
Heterocycles as ligands. X. 2,2',5,5'-Tetra-tert-butyl-1,1'-diazaferrocene. Stabilization of the diheterometallocene structure by steric shielding.
1991
In: Chemische Berichte (Chem.Ber.), Jg. 124 (1991), Heft 1, S. 89 - 91
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Heterocycles as ligands. X. 2,2',5,5'-Tetra-tert-butyl-1,1'-diazaferrocene. Stabilization of the diheterometallocene structure by steric shielding.
Autor(in):
Kuhn, Norbert; Jendral, Kai; Boese, Roland im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen; Blaeser, Dieter
Erscheinungsjahr:
1991
Erschienen in:
Chemische Berichte (Chem.Ber.), Jg. 124 (1991), Heft 1, S. 89 - 91
ISSN:

Abstract:

Stable title compd. I was prepd. in 56% yield by the reaction of the corresponding lithiopyrrole with FeCl2. The x-ray anal. of I reveals a distorted sandwich structure influenced by repulsive interactions presumably both between the N atoms and the bulky Me3C substituents.