Kuhn, Norbert; Kratz, Thomas; Blaeser, Dieter; Boese, Roland:
Heterocycles as ligands. 21 1. Stable titanium carbene complexes.
1995
In: Inorganica Chimica Acta (Inorg.Chim.Acta), Jg. 238 (1995), Heft 1-2, S. 179 - 181
Artikel/Aufsatz in Zeitschrift1995Chemie
Titel:
Heterocycles as ligands. 21 1. Stable titanium carbene complexes.
Autor(in):
Kuhn, Norbert; Kratz, Thomas; Blaeser, Dieter; Boese, RolandLSF
Erscheinungsjahr
1995

Abstract:

The Ti carbene complexes I (R = Me, Et, CHMe2) are obtained by the reaction of the imidazol-2-ylidenes with TiCl4 in good yields. Careful hydrolysis of I (R = CHMe2) gives the dinuclear complex II (R = CHMe2) which was characterized by x-ray crystallog. and in which two complex fragments of pentacoordinated Ti are connected by a near linear O bridge.