Kuhn, Norbert; Kuhn, Annette; Boese, Roland; Augart, Norbert:

(C7H13BF2N2)Cr(CO)3: a vinamidine (1,5-diazapenta-1,3-diene)boron difluoride as a cyclohexadienide type ligand.

In: Journal of the Chemical Society, Chemical Communications, (1989) ; Nr. 15, S. 975-976
ISSN: 0022-4936
Zeitschriftenaufsatz / Fach: Chemie
The vinamidine boron difluoride (difluorodiazaborinane) (I) acts as a 6-electron donor ligand in the chromium tricarbonyl complex (II); the X-ray structure of II shows I to be a ligand analogous to cyclohexadienide.