Kuhn, Norbert; Schulten, Michael; Boese, Roland; Blaeser, Dieter:
Heterocycles as ligands. XII. Synthesis and structure of (C28H40N)MgC2H5.2C4H8O. Stabilization of a monomeric organomagnesium amide by steric crowding.
1991
In: Journal of Organometallic Chemistry, Jg. 421 (1991), Heft 1, S. 1 - 8
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Heterocycles as ligands. XII. Synthesis and structure of (C28H40N)MgC2H5.2C4H8O. Stabilization of a monomeric organomagnesium amide by steric crowding.
Autor(in):
Kuhn, Norbert; Schulten, Michael; Boese, Roland im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen; Blaeser, Dieter
Erscheinungsjahr:
1991
Erschienen in:
Journal of Organometallic Chemistry, Jg. 421 (1991), Heft 1, S. 1 - 8
ISSN:

Abstract:

Ethyl(1,3,6,8-tetra-tert-butylcarbazolyl)magnesium (I) is obtained as its monomeric THF adduct by the reaction of 1,3,6,8-tetra-tert-butylcarbazole with diethylmagnesium in THF. The x-ray structure of I reveals a strongly distorted terminal coordination (carbz-N-Mg 117.4 Deg) of the carbazolyl ligand.