Maier, Gunther; Seipp, Ulrich; Boese, Roland:
Isolation and crystal structure analysis of a titanium tetrachloride complex of a 1,3-diketone.
1987
In: Tetrahedron letters (Tetrahedron Lett.), Jg. 28 (1987), Heft 39, S. 4515 - 4516
Artikel/Aufsatz in Zeitschrift1987Chemie
Titel:
Isolation and crystal structure analysis of a titanium tetrachloride complex of a 1,3-diketone.
Autor(in):
Maier, Gunther; Seipp, Ulrich; Boese, RolandLSF
Erscheinungsjahr
1987

Abstract:

TiCl4 forms a cryst. adduct with MeCOCMe2COMe. This observation, together with the crystal structural data of the chelate formed, can explain the directive force of TiCl4 in stereoselective redns. of diketones.