Maier, Gunther; Seipp, Ulrich; Boese, Roland:

Isolation and crystal structure analysis of a titanium tetrachloride complex of a 1,3-diketone.

In: Tetrahedron letters (Tetrahedron Lett.), Jg. 28 (1987) ; Nr. 39, S. 4515-4516
ISSN: 0040-4039
Zeitschriftenaufsatz / Fach: Chemie
TiCl4 forms a cryst. adduct with MeCOCMe2COMe. This observation, together with the crystal structural data of the chelate formed, can explain the directive force of TiCl4 in stereoselective redns. of diketones.

Dieser Eintrag ist freigegeben.