Maier, Gunther; Seipp, Ulrich; Boese, Roland:

Isolation and crystal structure analysis of a titanium tetrachloride complex of a 1,3-diketone.

In: Tetrahedron letters (Tetrahedron Lett.), Jg. 28 (1987) ; Nr. 39, S. 4515-4516
ISSN: 0040-4039
Zeitschriftenaufsatz / Fach: Chemie
TiCl4 forms a cryst. adduct with MeCOCMe2COMe. This observation, together with the crystal structural data of the chelate formed, can explain the directive force of TiCl4 in stereoselective redns. of diketones.