Maier, Nadja; Schiewe, Joerg; Matschiner, Hermann; Maschmeier, Claus-Peter; Boese, Roland:
Structure of SO2/secondary amine complexes.
1994
In: Phosphorus, Sulfur and Silicon and the Related Elements, Jg. 91 (1994), Heft 1-4, S. 179 - 188
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Structure of SO2/secondary amine complexes.
Autor(in):
Maier, Nadja; Schiewe, Joerg; Matschiner, Hermann; Maschmeier, Claus-Peter; Boese, Roland im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen
Erscheinungsjahr:
1994
Erschienen in:
Phosphorus, Sulfur and Silicon and the Related Elements, Jg. 91 (1994), Heft 1-4, S. 179 - 188
ISSN:

Abstract:

The structure and the phys. properties of the complexes of SO2 with dimethylamine (complex 1) and piperidine (complex 2) were examd. X-ray anal. showed that 1 and 2 are stable charge-transfer complexes. This could be confirmed by UV and IR spectroscopy. Complex 1, which is a yellowish liq. at room temp., shows a remarkably high sp. cond. of 4.16 mS/cm (25 Deg). The sp. cond. of 1 in mixts. with several org. solvents is discussed in relation to the dynamic structural changes.