Mueller, J.; Paetzold, P.; Boese, R.:
The reaction of decaborane with hydrazoic acid: a novel access to azaboranes.
1990
In: Heteroatom Chemistry, Jg. 1 (1990), Heft 6, S. 461 - 465
Artikel/Aufsatz in Zeitschrift1990Chemie
Titel:
The reaction of decaborane with hydrazoic acid: a novel access to azaboranes.
Autor(in):
Mueller, J.; Paetzold, P.; Boese, R.LSF
Erscheinungsjahr
1990

Abstract:

The reaction of B10H12(SMe2)2 with HN3 yields arachno-B10H12(N3)(NH2) (I), a product with a m-NH2 group. I can be hydrolyzed to give the known arachno-B9H13(NH3). nido-NB9H11(N3) is formed from I by a deprotonation/protonation sequence. The azaborane nido-NB10H13 is a product of the thermolysis of I. The structure of I was elucidated by an x-ray structure anal.