Thiocyanation of 1,6-methanoannulene.
The thiocyanation of 1,6-methanoannulene (I, R = H) affords, in addn. to the thiocyanate I (R = thiocyanato), the unexpected isothiocyanato isomer I (R = isothiocyanato), as well as the abnormal diisothiocyanate addn. product II. The structure of II is supported by x-ray anal. data.
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