Neidlein, Richard; Constantinescu, Take; Boese, Roland; Blaeser, Dieter:

Thiocyanation of 1,6-methano[10]annulene.

In: Chemische Berichte (Chem.Ber.), Jg. 121 (1988) ; Nr. 9, S. 1699-1702
ISSN: 0009-2940
Zeitschriftenaufsatz / Fach: Chemie
The thiocyanation of 1,6-methano[10]annulene (I, R = H) affords, in addn. to the thiocyanate I (R = thiocyanato), the unexpected isothiocyanato isomer I (R = isothiocyanato), as well as the abnormal diisothiocyanate addn. product II. The structure of II is supported by x-ray anal. data.