Niesmann, Joerg; Klingebiel, Uwe; Noltemeyer, Mathias; Boese, Roland:

From monomeric iminosilane to a monomeric aminoalane: synthesis and crystal structures.

In: Chemical Communications (Cambridge), (1997) ; Nr. 4, S. 365-366
ISSN: 1359-7345
Zeitschriftenaufsatz / Fach: Chemie
The reaction between the iminosilane R2Si:NR' [R = CMe3, R' = Si(CMe3)2Ph] and AlMe3 in n-hexane at -78 Deg affords the 1st monomeric aminodimethylalane, Me2AlNR'R'' [R'' = Si(CMe3)2Me] (2); the crystal structure of 2 is presented.