Raharinirina, Annie; Boese, Roland; Schmid, Guenter:
Syntheses and crystal structures of two bulky aminohalostannanes, [(Me3Si)2CH]2Sn(Cl)N(H)(C6H2-2,4,6-tert-Bu3) and [(Me3Si)2CH]2Sn(F)N(H)(C6H2-2,4,6-tert-Bu3).
1990
In: Journal of Organometallic Chemistry, Jg. 395 (1990), Heft 1, S. 39 - 45
Artikel/Aufsatz in Zeitschrift1990Chemie
Titel:
Syntheses and crystal structures of two bulky aminohalostannanes, [(Me3Si)2CH]2Sn(Cl)N(H)(C6H2-2,4,6-tert-Bu3) and [(Me3Si)2CH]2Sn(F)N(H)(C6H2-2,4,6-tert-Bu3).
Autor(in):
Raharinirina, Annie; Boese, RolandLSF; Schmid, GuenterLSF
Erscheinungsjahr
1990
Erschienen in:
Titel:
Journal of Organometallic Chemistry
in:
Jg. 395 (1990), Heft 1, S. 39 - 45
ISSN:

Abstract:

The sterically hindered aminohalostannanes (Bis)2Sn(X)N(H)Ar [X = Cl, F; Bis = (Me3Si)2CH; Ar = 2,4,6-(Me3C)3C6H2] were prepd. in good yield by the reactions of the lithium salt of the amine ArNH2 with the (Bis)2SnX2. Their NMR spectra (1H, 19F, 119Sn) are described. The structures of these new compds. have been detd. by x-ray crystallog.