Rittinger, Stefan; Buchholz, Dirk; Delville-Desbois, Marie Helene; Linares, Jorge; Varret, Francois; Boese, Roland; Zsolnai, Laszlo; Huttner, Gottfried; Astruc, Didier:
Decamethylbimetallocenes.
1992
In: Organometallics, Jg. 11 (1992), Heft 4, S. 1454 - 1456
Artikel/Aufsatz in Zeitschrift1992Chemie
Titel:
Decamethylbimetallocenes.
Autor(in):
Rittinger, Stefan; Buchholz, Dirk; Delville-Desbois, Marie Helene; Linares, Jorge; Varret, Francois; Boese, RolandLSF; Zsolnai, Laszlo; Huttner, Gottfried; Astruc, Didier
Erscheinungsjahr
1992

Abstract:

Decamethylbimetallocenes e.g., (I), have been synthesized for Fe, Co, and Rh, and the crystal structures of the 36-electron iron and rhodium complexes show a fully transoid conformation; electron-transfer studies indicate the 35-electron mixed-valence PF6- diiron salt is localized and suggest the neutral dicobalt and dirhodium bis-sandwich species have resp. 38 and 36 valence electrons.