Roth, Wolfgang R.; Winzer, Markus; Lennartz, Hans Werner; Boese, Roland:
Energy well of the orthogonal trimethylenemethane. 1-Methylene-2-phenylcyclopropane thermolysis.
1993
In: Chemische Berichte (Chem.Ber.), Jg. 126 (1993), Heft 12, S. 2717 - 2725
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Energy well of the orthogonal trimethylenemethane. 1-Methylene-2-phenylcyclopropane thermolysis.
Autor(in):
Roth, Wolfgang R.; Winzer, Markus; Lennartz, Hans Werner; Boese, Roland im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen
Erscheinungsjahr
1993
Erschienen in:
Chemische Berichte (Chem.Ber.), Jg. 126 (1993), Heft 12, S. 2717 - 2725
ISSN

Abstract:

From the heat of hydrogenation of title compd. I, the activation enthalpy for the racemization of I, and the oxygen dependence of the trapping rate of the intermediate diradical II, the energy profile for the degenerate methylenecyclopropane rearrangement can be constructed, which leads to heats of formation for the triplet and singlet state of II of 93.9 and 95.6 kcal mol-1, resp.