Schmid, Guenter; Vehreschild-Yzermann, Dorothee; Boese, Roland:

Synthesis and study of 1,3-di-tert-butyl-2,4-dimethyl-1,3-diaza-2,4-diborolidine.

In: Journal of Organometallic Chemistry, Jg. 326 (1987) ; Nr. 3, S. 307-314
ISSN: 0022-328X
Zeitschriftenaufsatz / Fach: Chemie
Abstract:
Cyclocondensation of MeB(NHCMe3)2 with Me2Sn(CH2Br)Br in presence of BuLi-Et2O gave 60% stannaborolidine I. Reaction of I with MeBBr2 in pentane gave an adduct, which on refluxing in THF, gave 15% title compd. II. The structure of I was detd. by x-ray crystallog.