Schneider, Joerg J.; Hagen, Joerg; Blaeser, Dieter; Boese, Roland; Krueger, Carl:
The reactivity of the unbridged Co-Sn bond in [(h5-C5H5)(h2-C2H4)Co-Sn{CH[Si(CH3)3]2}2] - the first organometallic complexes with direct Co-Sn-chalcogen bonding (chalcogen = Se, Te).
1997
In: Angewandte Chemie, International Edition in English, Jg. 36 (1997), Heft 7, S. 739 - 741
Artikel/Aufsatz in Zeitschrift1997Chemie
Titel:
The reactivity of the unbridged Co-Sn bond in [(h5-C5H5)(h2-C2H4)Co-Sn{CH[Si(CH3)3]2}2] - the first organometallic complexes with direct Co-Sn-chalcogen bonding (chalcogen = Se, Te).
Autor(in):
Schneider, Joerg J.LSF; Hagen, Joerg; Blaeser, Dieter; Boese, RolandLSF; Krueger, Carl
Erscheinungsjahr
1997

Abstract:

Reaction of [(h5-C5R5)Co(h2-C2H4)2] (R = H, Me) with [Sn{CH(SiMe3)2}2] leads to formation of [(h5-C5R5)(h2-C2H4)Co-Sn{CH(SiMe3)2}2] (I). The crystal structure of I (R = H) was detd. Reaction of I (R = H) with X (X = Se, Te) in PhMe gave [(h5-C5H5)CoX{Sn(CH(SiMe3)2)2}2] (II) with first cobalt-tin-chalcogen bond. The crystal structure of II were also detd.