Stanger, Amnon; Schachter, Alona; Ashkenazi, Nissan; Boese, Roland; Stellberg, Peter:
Nickel mediated cyclobutabenzenes syntheses.
1997
In: Organic Synthesis via Organometallics, Proceedings of the Symposium, 5th, Heidelberg, Sept.26-28, 1996, S. 59 - 66
Artikel/Aufsatz in Zeitschrift1997Chemie
Titel:
Nickel mediated cyclobutabenzenes syntheses.
Autor(in):
Stanger, Amnon; Schachter, Alona; Ashkenazi, Nissan; Boese, RolandLSF; Stellberg, Peter
Erscheinungsjahr
1997
Erschienen in:
Titel:
Organic Synthesis via Organometallics, Proceedings of the Symposium, 5th, Heidelberg, Sept.26-28, 1996
in:
S. 59 - 66

Abstract:

Nickel-mediated cyclobutabenzene synthesis was proven to be useful in the stereoselective synthesis of trans-dibromocyclobutabenzene, bicyclobutabenzene and tricyclobutabenzene. The systems obtained were functionalized in four-membered rings and allow further transformation of these compds. This methodol. allows new entries to org. synthesis of polycyclic compds. and polymer chem. and to the prepn. of compds. relevant to the study of the Mills-Nixon effect. The crystal and mol. structure of of tris(tricarbonyliron)benzotricyclobutadiene were reported.