Stein, D.; Sitzmann, H.; Boese, R.:
Charge transfer-complexes of octaethylferrocene.
1991
In: Journal of Organometallic Chemistry, Jg. 421 (1991), Heft 2-3, S. 275 - 283
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Charge transfer-complexes of octaethylferrocene.
Autor(in):
Stein, D.; Sitzmann, H.; Boese, R. im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen
Erscheinungsjahr:
1991
Erschienen in:
Journal of Organometallic Chemistry, Jg. 421 (1991), Heft 2-3, S. 275 - 283
ISSN:

Abstract:

The reaction of octaethylferrocene (I) with 7,7',8,8'-tetracyano-p-quinodimethane (TCNQ) gives a 1:1 charge-transfer complex [(C5Et4H)2Fe]+ [TCNQ]- (II). The crystal structure of II has been detd. at 110 K and shown to consist of one-dimensional D+A-D+... stacks. The reaction of I with 2,3,5,6-tetrafluoro-7,7',8,8'-tetracyano-p-quinodimethane (TCNQ-F4) gives a 1:1 charge-transfer complex with dimeric anion, the crystal structure of which is also detd. at 103 K. The known charge-transfer complex of decaethylferrocene with TCNQ has independently been subjected to a crystal structure anal. at 110 K.