Stein, D.; Sitzmann, H.; Boese, R.; Dormann, E.; Winter, H.:

A charge-transfer complex of decaethylferrocene with 2,3,5,6-tetrafluoro-7,7',8,8'-tetracyano-p-quinodimethane.

In: Journal of Organometallic Chemistry, Jg. 412 (1991) ; Nr. 1-2, S. 143-155
ISSN: 0022-328X
Zeitschriftenaufsatz / Fach: Chemie
Reaction of decaethylferrocene with 2,3,5,6-tetrafluoro-7,7',8,8'-tetracyano-p-quinodimethane (TCNQ-F4) in MeCN at 40 Deg gave 40% 1:1 charge-transfer complex with dimeric anion, the crystal structure of which were detd. The magnetic susceptibility of the charge-transfer complex from 300 K to 1.7 K is consistent with the Curie-Weiss law without an indication of magnetic ordering.