Sustmann, Reiner; Hopp, Peter; Boese, Roland:
Preparation, crystal structure and reactivity of bis(methyl acrylate)(pyridine)nickel(0).
1989
In: Journal of Organometallic Chemistry, Jg. 375 (1989), Heft 2, S. 259 - 264
Artikel/Aufsatz in Zeitschrift1989Chemie
Titel:
Preparation, crystal structure and reactivity of bis(methyl acrylate)(pyridine)nickel(0).
Autor(in):
Sustmann, Reiner; Hopp, Peter; Boese, RolandLSF
Erscheinungsjahr
1989

Abstract:

The prepn., crystal structure and reactivity of bis(Me acrylate)(pyridine)nickel(0) are reported. This complex reacts with E,Z-1-bromo-1-propene in the presence of water to give the conjugate addn. product. Complexes of this type seem to be involved in Ni(0) catalyzed reactions of olefins with org. halides in the presence of pyridine and water.