Weber, Lothar; Bungardt, Dagmar; Boese, Roland; Blaeser, Dieter:
Transition-metal functionalized phosphaarsenes (h5-C5H4R)(CO)(PPh3)Fe-As:P-[C6H2(tertBu)3-2,4,6] (R = H, Me) and 1,3,2,4-diphosphadiarsetanes [(h5-C5Me5)(CO)2Fe-(cyclic As-P)-(C6H2Me3-2,4,6)]2.
1988
In: Chemische Berichte (Chem.Ber.), Jg. 121 (1988), Heft 6, S. 1033 - 1038
Artikel/Aufsatz in Zeitschrift / Fach: Chemie
Titel:
Transition-metal functionalized phosphaarsenes (h5-C5H4R)(CO)(PPh3)Fe-As:P-[C6H2(tertBu)3-2,4,6] (R = H, Me) and 1,3,2,4-diphosphadiarsetanes [(h5-C5Me5)(CO)2Fe-(cyclic As-P)-(C6H2Me3-2,4,6)]2.
Autor(in):
Weber, Lothar; Bungardt, Dagmar; Boese, Roland im Online-Personal- und -Vorlesungsverzeichnis LSF anzeigen; Blaeser, Dieter
Erscheinungsjahr:
1988
Erschienen in:
Chemische Berichte (Chem.Ber.), Jg. 121 (1988), Heft 6, S. 1033 - 1038
ISSN:

Abstract:

The title phosphaarsenes (h5-C5H4R)Fe(CO)(PPh3)[As:PC6H2(CMe3)3-2,4,6] (R = H, Me; C5H5 = cyclopentadienyl) were formed in the reaction of (h5-C5H4R)Fe(CO)(PPh3)[As(SiMe3)2] with 2,4,6-(Me3C)3C6H2PCl2. Treating (h5-C5Me5)Fe(CO)2[As(SiMe3)2] with 2,4,6-Me3C6H2PCl2 gave the first transition-metal functionalized 1,3,2,4-diphosphadiarsetane I, which was characterized by x-ray crystallog.